Crystal structure and Hirshfeld surface analysis of 5-acetyl-3-amino-6-methyl-N-phenyl-4-[(E)-2-phenylethenyl]thieno[2,3-b]pyridine-2-carboxamide

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Mohamed S. K., Bakhite E. A., Çelikesir S. T., Abdu-Allah H. H. M., AKKURT M., Ibrahim O. F., ...More

Acta Crystallographica Section E: Crystallographic Communications, vol.78, pp.225-230, 2022 (ESCI, Scopus)

• Publication Type: Article / Article
• Volume: 78
• Publication Date: 2022
• Doi Number: 10.1107/s2056989022000743
• Journal Name: Acta Crystallographica Section E: Crystallographic Communications
• Journal Indexes: Emerging Sources Citation Index (ESCI), Scopus
• Page Numbers: pp.225-230
• Keywords: crystal structure, styryl group, thiopyridine, N-phenylcarboxamido group, C-H center dot center dot center dot pi(ring) interactions, Hirshfeld surface analysis, THIENOPYRIDINES, DERIVATIVES, CHEMISTRY
• Open Archive Collection: AVESIS Open Access Collection
• Kayseri University Affiliated: No

Abstract

© 2022.The asymmetric unit of the title compound, C25H21N3O2S, comprises four molecules. Their conformations differ primarily in the orientations of the styryl and the N-phenylcarboxamido groups. In the crystal, intermolecular N - H⋯N, C - H⋯O and C - H⋯S hydrogen-bonding contacts as well a C - H⋯π(ring) interactions lead to the formation of a layer structure parallel to (010). Hirshfeld surface analysis revealed that H⋯H interactions represent the main contributions to the crystal packing.