Crystal structure and Hirshfeld surface analysis of 2-(4-chlorophenyl)-4-(dimethoxymethyl)-5-phenyl-1,3-thiazole

Guseinov, Firudin; Kobrakov, Konstantin; Shuvalova, Elena; Tuzharov, Egor; AKKURT, MEHMET; Yildirim, Sema; Bhattarai, Ajaya; Harrison, W.T.A.

doi:10.1107/s2056989022005564

Crystal structure and Hirshfeld surface analysis of 2-(4-chlorophenyl)-4-(dimethoxymethyl)-5-phenyl-1,3-thiazole

Guseinov F. I., Kobrakov K. I., Shuvalova E. V., Tuzharov E. I., AKKURT M., Yildirim S. Ö., ...Daha Fazla

Acta Crystallographica Section E: Crystallographic Communications, cilt.78, sa.Pt 6, ss.675-678, 2022 (ESCI, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 78 Sayı: Pt 6
Basım Tarihi: 2022
Doi Numarası: 10.1107/s2056989022005564
Dergi Adı: Acta Crystallographica Section E: Crystallographic Communications
Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
Sayfa Sayıları: ss.675-678
Anahtar Kelimeler: crystal structure, thiazole ring, chlorophenyl ring, C-H center dot center dot center dot pi interactions, Hirshfeld surface analysis
Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
Kayseri Üniversitesi Adresli: Hayır

Özet

© 2022 Guseinov et al.In the title compound, C18H16ClNO2S, the thiazole ring subtends dihedral angles of 13.12 (14) and 43.79 (14) ° with the attached chlorophenyl and phenyl rings, respectively. In the crystal, C-Hπ interactions link the molecules, forming a three-dimensional network. The roles of the various intermolecular interactions were clarified by Hirshfeld surface analysis, which reveals that the most important contributions to the crystal packing are from HH (39.2%), HC/CH (25.2%), ClH/HCl (11.4%) and OH/HO (8.0%) contacts.