Crystal structure and Hirshfeld surface analysis of 2-(4-chlorophenyl)-4-(dimethoxymethyl)-5-phenyl-1,3-thiazole

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Guseinov F. I., Kobrakov K. I., Shuvalova E. V., Tuzharov E. I., AKKURT M., Yildirim S. Ö., ...More

Acta Crystallographica Section E: Crystallographic Communications, vol.78, no.Pt 6, pp.675-678, 2022 (ESCI) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 78 Issue: Pt 6
  • Publication Date: 2022
  • Doi Number: 10.1107/s2056989022005564
  • Journal Name: Acta Crystallographica Section E: Crystallographic Communications
  • Journal Indexes: Emerging Sources Citation Index (ESCI), Scopus
  • Page Numbers: pp.675-678
  • Keywords: crystal structure, thiazole ring, chlorophenyl ring, C-H center dot center dot center dot pi interactions, Hirshfeld surface analysis
  • Kayseri University Affiliated: No


© 2022 Guseinov et al.In the title compound, C18H16ClNO2S, the thiazole ring subtends dihedral angles of 13.12 (14) and 43.79 (14) ° with the attached chlorophenyl and phenyl rings, respectively. In the crystal, C-Hπ interactions link the molecules, forming a three-dimensional network. The roles of the various intermolecular interactions were clarified by Hirshfeld surface analysis, which reveals that the most important contributions to the crystal packing are from HH (39.2%), HC/CH (25.2%), ClH/HCl (11.4%) and OH/HO (8.0%) contacts.