Synthesis and characterization of conducting copolymer of Trans-1-(4-methyl-3'-thienyl)-2-(ferrocenyl)ethene with EDOT

TURAC E., Sahmetlioglu E., DEMIRCAN A., Toppare L.

JOURNAL OF APPLIED POLYMER SCIENCE, cilt.126, sa.3, ss.808-814, 2012 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 126 Sayı: 3
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1002/app.36948
  • Dergi Adı: JOURNAL OF APPLIED POLYMER SCIENCE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.808-814
  • Anahtar Kelimeler: ferrocene, EDOT, AFM, copolymerization, CONJUGATED POLYMERS, OPTOELECTROCHEMICAL PROPERTIES, FILMS, DERIVATIVES, ELECTROPOLYMERIZATION, NANOPARTICLES, CATIONS
  • Kayseri Üniversitesi Adresli: Hayır

Özet

Ferrocene-substituted conducting polymer namely poly(trans-1-(4-methyl-3'-thienyl)-2-(ferrocenyl)ethene-co-3,4-ethylenedioxythiophene) [P(MTFE-co-EDOT)] was synthesized and its electrochromic properties were studied. Monomer, MTFE, was obtained using 2-(ferrocenyl)ethene and 3-methyl-4-bromothiophene. The structure of monomer was determined via Fourier transform infrared spectroscopy (FTIR), 1H-NMR, and 13C-NMR techniques. The copolymer was synthesized using this monomer and EDOT. The resulting copolymer P(MTFE-co-EDOT) was characterized by cyclic voltammetry, FTIR, scanning electron microscopy, atomic force microscopy, and UVvis spectroscopy. The conductivity measurements of copolymer and PEDOT were accomplished by the four-probe technique. Although poly(trans-1-(4-methyl-3'-thienyl)-2-(ferrocenyl)ethene) [P(MTFE)] reveals no electrochromic activity, its copolymer with EDOT has two different colors (violet and gray). Band gap (Eg) and ?max of P(MTFE-co-EDOT) were determined. (c) 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012