A synthesized ternary polymer composite and its use for SPE of trace metals in Coffee, tea and legumes

DAŞBAŞI T., Soykan C.

FOOD CHEMISTRY, cilt.365, 2021 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 365
  • Basım Tarihi: 2021
  • Doi Numarası: 10.1016/j.foodchem.2021.130518
  • Dergi Adı: FOOD CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Aerospace Database, Aquatic Science & Fisheries Abstracts (ASFA), BIOSIS, CAB Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, EMBASE, Food Science & Technology Abstracts, MEDLINE, Metadex, Veterinary Science Database, Civil Engineering Abstracts
  • Anahtar Kelimeler: Ternary polymer composite, Trace metals, Solid phase extraction, Flame atomic absorption spectrometry, SOLID-PHASE EXTRACTION, CARBON NANOTUBES, FOOD SAMPLES, ROUGHNESS, IONS, TRANSPORT, SURFACES, NI(II), CU(II), FAAS
  • Kayseri Üniversitesi Adresli: Evet

Özet

A new synthesized ternary polymer composite, polystyrene/polyacrylonitrile/polyindole (PSt/PAN/PIN), was used as an adsorbent. The structure of synthesized composite was supported by FTIR, BET, X-RD, TGA, SEM and AFM technique. A SPE method with synthesized composite was developed for the preconcentration of chromium, copper, iron, manganese, lead and zinc ions. The adsorption capacity were found in the range of 37.4-56.7 mg g(-1). Under the best conditions, the preconcentration factor of method was found as 100. Relative standard deviation was found at <= 3.3% (n = 11). The detection limits of analytes were obtained as: 0.9 mu g L-1 for Cr(III), 1.2 mu g L-1 for Cu(II), 2.0 mu g L-1 for Fe(III), 1.4 mu g L-1 for Mn(II), 0.9 mu g L-1 for Pb(II) and 2.0 mu g L-1 for Zn(II). Firstly, this SPE method was applied to certified reference material, and than coffee, tea, legumes. The trace metals was analyzed by flame atomic absorption spectrometry.