Multichromic conducting copolymer of 1-benzyl-2,5-di(thiophen-2-yl)-1H-pyrrole with EDOT

ÇAMURLU P., Tarkuc S., Sahmetlioglu E., Akhmedov I. M., TANYELİ C., Toppare L.

SOLAR ENERGY MATERIALS AND SOLAR CELLS, vol.92, no.2, pp.154-159, 2008 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 92 Issue: 2
  • Publication Date: 2008
  • Doi Number: 10.1016/j.solmat.2006.12.020
  • Journal Name: SOLAR ENERGY MATERIALS AND SOLAR CELLS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.154-159
  • Keywords: electrochemical copolymerization, electrochromism, 1-benzyl-2,5-di(thiophen-2-yl)-1H-pyrrole, 3,4-ethylenedioxythiophene, multichromism, electrochromic devices, POLYMER
  • Kayseri University Affiliated: No

Abstract

Despite the significant progress made in the field of electrochromic polymers, the multichromic facility of current knowledge is restricted. Therefore, as previously proven, electrochemical copolymerization of 1-benzyl-2,5-di(thiophen-2-yl)-1H-pyrrole (SNBS) and 3,4-ethylenedioxythiophene (EDOT) was used as a strategy to achieve desired multichromic properties, where the resultant copolymer displayed distinct color changes between claret red, yellow, green, and blue colors with short switching times and high optical contrast. As an application, absorption/transmission type electrochromic device with indium. tin oxide (ITO)/copolymer/gel electrolyte PEDOT/ITO configuration was constructed, where copolymer and PEDOT functioned as the anodically and the cathodically coloring layers, respectively. Results implied the successive use of this copolymer in electrochromic device applications, since the device exhibited short switching times with a wide color variation upon applied potential. (c) 2007 Elsevier B.V. All rights reserved.