Crystal structure and Hirshfeld surface analysis of 2,2′-(phenylazanediyl)bis(1-phenylethan-1-one)

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Naghiyev F. N., Khrustalev V. N., Safronenko M. G., AKKURT M., Khalilov A. N., Bhattarai A., ...More

Acta Crystallographica Section E: Crystallographic Communications, vol.78, pp.691-694, 2022 (ESCI) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 78
  • Publication Date: 2022
  • Doi Number: 10.1107/s2056989022005382
  • Journal Name: Acta Crystallographica Section E: Crystallographic Communications
  • Journal Indexes: Emerging Sources Citation Index (ESCI), Scopus
  • Page Numbers: pp.691-694
  • Keywords: crystal structure, C-H center dot center dot center dot O hydrogen bonds, C-H center dot center dot center dot pi interactions, van der Waals interactions, Hirshfeld surface
  • Kayseri University Affiliated: No

Abstract

© 2022 Published under a CC BY 4.0 licence.The whole molecule of the title compound, C22H19NO2, is generated by twofold rotational symmetry. The N atom exhibits a trigonal-planar geometry and is located on the twofold rotation axis. In the crystal, molecules are linked by C-H⋯O contacts with R 2 2(12) ring motifs, and C-H⋯π interactions, resulting in ribbons along the c-axis direction. van der Waals interactions between these ribbons consolidate the molecular packing. Hirshfeld surface analysis indicates that the greatest contributions to the crystal packing are from H⋯H (45.5%), C⋯H/H⋯C (38.2%) and O⋯H/H⋯O (16.0%) interactions.