Preconcentrations of Cu (II) and Mn (II) by magnetic solid-phase extraction on Bacillus cereus loaded γ-Fe2O3 nanomaterials

Ozdemir S., Turkan Z., Kilinc E., Bayat R., SOYLAK M., Sen F.

Environmental Research, cilt.209, 2022 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 209
  • Basım Tarihi: 2022
  • Doi Numarası: 10.1016/j.envres.2022.112766
  • Dergi Adı: Environmental Research
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Aerospace Database, Applied Science & Technology Source, Aqualine, Aquatic Science & Fisheries Abstracts (ASFA), Artic & Antarctic Regions, BIOSIS, CAB Abstracts, Chemical Abstracts Core, Communication Abstracts, Computer & Applied Sciences, EMBASE, Environment Index, Geobase, Greenfile, MEDLINE, Metadex, Pollution Abstracts, Public Affairs Index, Veterinary Science Database, Civil Engineering Abstracts
  • Anahtar Kelimeler: Bacillus cereus, ICP-OES, Preconcentration, Magnetic nanoparticle, Solid-phase extraction, HEAVY-METALS, WASTE-WATER, REMOVAL
  • Kayseri Üniversitesi Adresli: Hayır

Özet

© 2022 Elsevier Inc.For the simultaneous preconcentrations of Cu(II) and Mn(II), a novel preconcentration technique was developed and described. Bacillus cereus loaded magnetic ɣ-Fe2O3 nanoparticles were prepared and used as support materials on solid-phase extraction procedure. Important experimental parameters were investigated in details and pH 6.0, 3 mL min−1 of flow rate, 5 mL of 1 mol L−1 of HCl as eluent, 200 mg of biomass, and 200 mg of magnetic ɣ-Fe2O3 nanoparticles as support material was found as the best conditions. The preconcentrations factor were found to be 80 for Cu (II) and Mn(II). It was confirmed by the results that SPE columns could be used in 32 cycles. The LOD values calculated for Cu (II) and Mn (II) were 0.09 and 0.08 ng mL−1, respectively. The RSD values found were less than 3.4%. The extraction recoveries were achieved as higher than 98%. The biosorption capacities of Cu (II), and Mn (II) were 26.0 mg g−1, 30.3 mg g−1 respectively. The approach devised for analyzing analyte concentrations in food samples proved to be successful.