Investigation of the performance and properties of ZnO/GO double-layer supercapacitor


Buyukkurkcu H., Durmus A., Colak H., KURBAN R., Sahmetlioglu E., KARAKÖSE E.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, vol.191, 2024 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 191
  • Publication Date: 2024
  • Doi Number: 10.1016/j.jpcs.2024.111984
  • Journal Name: JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, Chimica, Compendex, INSPEC, Metadex
  • Kayseri University Affiliated: Yes

Abstract

Composite electrode material was formed by mixing reduced graphene oxide (rGO) and zinc oxide (ZnO) compound, using the Hummers and green synthesis methods, respectively. Of rGO powder, 10 g was mixed with 10%, 20% and 30% ZnO, and composite electrodes were obtained by using 10% binder. The energy storage performance and structural characteristics of the supercapacitor were evaluated by analyzing the capacitance values of the synthesized electrodes. The structural characterization of ZnO/rGO composites was performed using X-ray diffraction and field-emission scanning electron microscopy. The electrochemical properties of the ZnO/GO electrodes were analyzed by cyclic voltammetry, electrochemical impedance and galvanostatic charge -discharge tests. The specific capacitance value of electrodes increased as zinc content increased in the ZnO/ rGO composite material used to produce electrodes. The maximum specific capacitance values were measured at 5 mV/s scanning rate as 194.23 (rGO), 366.81 (10% ZnO), 383.18 (20% ZnO) and 410.48 F/g (30% ZnO). In conclusion, the use of composite material formed by the combination of ZnO nanoparticles obtained by green synthesis method from orange peel and graphene oxide increased the electrochemical efficiency of the supercapacitor.